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By Junzo Otera
Glossy Carbobyl Chemistry Junzo Otera (Ed.) The carbonyl staff is certainly essentially the most very important useful teams in natural chemistry, either in its position as reactive middle of synthesis or derivatisation and as the most important function for certain structural or physiological houses. significant and profound growth has been made in all elements of contemporary carbonyl chemistry. those achievements are, in spite of the fact that, really dispersed within the literature and it is usually tough for the researcher to procure a finished review of a proper subject. sleek Carbonyl Chemistry overcomes this inconvenience by way of collating the knowledge for acceptable subject matters. during this paintings the world over popular specialists and leaders within the box have surveyed fresh elements and sleek positive factors in carbonyl chemistry, resembling cascade-reactions, one-pot-synthesis, acceptance, or web site differentiation.
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Extra info for Modern Carbonyl Chemistry
Example text
The authors reported a new catalytic Meerwein-Ponndorf-Verley reduction [60,6I ] system based on the bidentate Lewis acid chemistry [62]. Treatment of benzaldehyde with (2,7-dimethyl-l,8-biphenylenedioxy)bis(diisopropoxyaluminum) (57) at room temperature instantaneously produced the reduced benzyl alcohol almost quantitatively (entry 2, Table 1-10>. This remarkable efficiency can be ascribed to the double electrophilic activation of carbonyls by the bidentate aluminum catalyst (Scheme 1-21). Other selected examples are summarized in Table 1-10.
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