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By J. P. Kamerling
Carbohydrates are an incredible a part of lifestyles and are found in micro organism, fungi, viruses, yeast, vegetation, animals and humans.
The fast growth of chemistry and glycobiology during the last few years has supplied many new, creative and effective thoughts which supply extra perception into the buildings and organic interactions of carbohydrates and glycostructures.
This paintings has a really vast scope and should entice a large viewers because it explores the interactions among biology, chemistry and molecular biology in the direction of realizing, synthesising and constructing glycoproteins, glycolipids, proteoglyans and polysaccharides, that are vital molecules in nature for controlling overall healthiness and sickness and nutrients and feed.
Glycocompounds reviewed contain: oligosaccharides, polysaccharides, glycoproteins, glycolipids, glycoconjugates, lectins, cellulose, pectins and starch.
Topics lined comprise: spectroscopy, nomenclature, constructions, synthesis, biosynthesis, molecular interactions, degradation, biochemistry, glycobiology, glycotherapeutics and diseases.
· Combines a number of points of glycoscience in a single entire work
· files the recent and fast growth of carbohydrate chemistry and glycobiology over the past few years
· Highlights the numerous new, ingenious and effective thoughts for offering insights into carbohydrates and glycostructures
Read or Download Comprehensive Glycoscience, Four-Volume Set: From Chemistry to Systems Biology PDF
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Carbohydrates are a tremendous a part of lifestyles and are found in micro organism, fungi, viruses, yeast, vegetation, animals and humans.
The swift enlargement of chemistry and glycobiology over the past few years has supplied many new, resourceful and effective suggestions which offer extra perception into the buildings and organic interactions of carbohydrates and glycostructures.
This paintings has a really huge scope and should entice a large viewers because it explores the interactions among biology, chemistry and molecular biology in the direction of knowing, synthesising and constructing glycoproteins, glycolipids, proteoglyans and polysaccharides, that are vital molecules in nature for controlling health and wellbeing and illness and meals and feed.
Glycocompounds reviewed contain: oligosaccharides, polysaccharides, glycoproteins, glycolipids, glycoconjugates, lectins, cellulose, pectins and starch.
Topics coated contain: spectroscopy, nomenclature, constructions, synthesis, biosynthesis, molecular interactions, degradation, biochemistry, glycobiology, glycotherapeutics and diseases.
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· records the recent and quick enlargement of carbohydrate chemistry and glycobiology over the past few years
· Highlights the numerous new, innovative and effective innovations for delivering insights into carbohydrates and glycostructures
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Additional info for Comprehensive Glycoscience, Four-Volume Set: From Chemistry to Systems Biology
Sample text
01. The monosaccharide–amino acid coupling products are defined as glycosyl-amino-acids and the proposed abbreviations are: (GlcNAc-)Asn, (GalNAc-)Ser, (GalNAc-)Thr, and so on. The parentheses around the monosaccharide are needed to indicate that the monosaccharide is connected to the functional group in the side chain of the amino acid instead of to the a-amino group of the amino acid. Full names are, for example, 2-acetamido-N-(L-aspart-4-yl)2-deoxy-b-D-glucopyranosylamine or N 4-(N-acetyl-b-D-glucosaminyl)asparagine for (GlcNAc-)Asn; 2-acetamido-O(L-ser-3-yl)-2-deoxy-a-D-galactopyranosylamine or O3-(N-acetyl-a-D-galactosaminyl)serine for (GalNAc-)Ser.
This means that sugar chains, but not nucleic acids and proteins, have the following characteristic feature: they can form multiple structures with a small number of units. In addition to the structural multiplicity, another factor makes the structural study of the sugar chains of glycoproteins difficult. Many glycoproteins contain more than one sugar chain in one molecule. Even in the case of a glycoprotein containing only one sugar chain, there is a widespread micro-heterogeneity1 in sugar chain structures since formation of incomplete chains is easily induced because of the absence of a template in the biosynthetic machinery of sugar chains.
The name of the compound in Figure 30d is 3-O-acetyl-4-O-benzoyl-2-O-methyla-D-mannopyranuronic acid, with a > b > m. In case of the corresponding methyl glycoside, the name becomes methyl 3-O-acetyl-4-O-benzoyl-2-O-methyl-a-D-mannopyranosiduronic acid, and in case of the sodium salt it becomes sodium (methyl 3-O-acetyl-4-O-benzoyl-2-O-methyl-a-D-mannopyranosid)uronate. The name of the compound in Figure 30e is 4-O-acetyl-3,6-di-O-benzyl-2-deoxy-2-phthalimido-a-D-glucopyranosyl trichloroacetimidate; for the alphabetical order of the groups, a > b > d > p, the prefix ‘di’ is ignored.