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By Mahmoud H. Hamdan, Pier G. Righetti
Nice, very modern in sthis rising box, has been (and nonetheless is) very usefull for me in my career. Recomended!
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Additional info for Proteomics Today: Protein Assessment and Biomarkers Using Mass Spectrometry, 2D Electrophoresis,and Microarray Technology
Sample text
This kinetic energy compensation would result in velocity focusing, allowing ions having the same mass to reach the detector at the same time regardless of their initial velocity at the time of their formation. 6. ION DETECTION Current literature leaves no doubt that detection is the component which has not kept pace with the development associated with new ionization techniques and new generation of analyzers. Microchannel plates (MCPs) are still the routine ion detectors of choice for TOF–MS.
Third, it is still unclear through what mechanism the analyte ions are formed and subsequently released from the porous surface. , 1998). Alternatively, as porous silicon absorbs hydrocarbons from air or while under vacuum, rapid heating/vaporization of trapped hydrocarbon contaminants or solvent molecules may contribute to the vaporization and ionization of the analyte embedded in the porous silicon (Canham, 1997). Fourth, there is an initial indication that the potential application of DIOS can be broad; however, such potential is strictly related to finding new surfaces which can be easily and efficiently derivatized to trap a wide range of analytes.
The same characteristic can be used to discriminate between fragments and their precursors. , 2001). Two types of cryogenic detectors, superconducting tunnel junctions (STJ) and low-temperature calorimeters, are briefly described here. 1. Superconducting Tunnel Junction This type of detector consists of two thin films of superconductors separated by a thin insulating barrier through which quantum mechanical tunneling of electrons can occur. 5a. It operates best at a temperature which has to be well below the critical temperature of the superconducting films.