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By Thierry Meyer, Jos Keurentjes
During this two-volume set, Meyer (polymer response engineering, Swiss Federal Institute of expertise, Switzerland) and Keurentjes (process improvement, Eindhoven collage of know-how) current the present country of information on polymer response engineering, from the monomer to the ultimate product. The set starts with an outline describing the combination of technology and engineering in polymer response engineering, then covers the technological know-how and chemistry of significant forms of polymerization, polymer response engineering instruments and techniques, and the physics and actual nature of shaped polymers. the main points of polymer end-use also are mentioned. procedure improvement, questions of safety, scale-up, and modeling are tested, and the set concludes with a evaluate of rising tactics. either editors are affiliated with the ecu Federation of Chemical Engineering.
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V. Schulz, Z. Physik. , 1935, B30, 379. P. J. Flory, J. Am. Chem. , 1936, 58, 1877. W. H. Carothers, US Patent 2 130 948, 1937. E. W. Fawcett, R. O. Gibson, J. Chem. , 1934, 386. K. G. Denbigh, Trans. , 1947, 43, 648. K. Ziegler, E. Holzkamp, H. Breil, H. Martin, Angew. , 1955, 67, 541. P. W. Morgan, S. L. Kwolek, Macromolecules, 1975, 8, 104. H. Sasabe, T. Wada, Polymers for electronic applications, in: Comprehensive Polymer Science, vol. 7, S. L. ), Pergamon Press, Oxford, 1989. J. K. J. van Duren, J.
2), which is characterized by the occurrence of a lower critical solution temperature (LCST) [9]. This phenomenon can not be explained on the basis of the original Flory–Huggins theory. Delmas and Patterson [10] calculated binary critical curves of polymer–solvent systems using the Flory equation of state [11, 12]. According to these authors the reason for the occurrence of this LCST is the large difference in thermal expansion of pure liquid polymer and pure solvent, which leads to an increasing difference in free volume with increasing temperature and an LCST-type liquid–liquid phase split at temperatures below the critical point of the solvent.
Nevertheless, we can observe that a great overlap is present in the middle zone, 10 1 Polymer Reaction Engineering, an Integrated Approach waste management Specification - technical - economic - ecologic - safety recycling Balances raw material product use - energy - material - emission - waste - sewage synthesis processing Evaluation leads to closed loop assessment of costs Fig. 8. Life cycle analysis of parts, methods, products, and systems. where interests, tools, and knowledge are similar, thus providing a strong basis for partnership.