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By Scott M. Auerbach, Kathleen A. Carrado, Prabir K. Dutta
This reference/text comprehensively explores clays and different periods of fabrics showing the facility to pillar, or determine everlasting intracrystalline porosity inside of layers-offering an authoritative presentation in their basic homes, summaries of state of the art learn effects, and descriptions of recent usages together with catalytic and photocatalytic purposes.
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In: ME Schrader, G Loeb, eds. Modern Approaches to Wettability. New York: Plenum Press, 1992:279–326. 59. C Walling. J Am Chem Soc 1950; 72:1164–1168. 60. HA Benesi. J Am Chem Soc 1956; 78:5490–5494. 61. JE Mapes, RP Eischens. J Phys Chem 1954; 58:1059–1062. 62. AC Wright, WT Granquist, JV Kennedy. J Catal 1972; 25:65–80. 63. JP Rupert, WT Granquist, TJ Pinnavaia. In: ACD Newman, ed. Chemistry of Clays and Clay Minerals. New York: Wiley Interscience, 1987:275–318. 64. WP Hettinger. Appl Clay Sci 1991; 5:445–468.
The relative degrees of surface acidity then depend strongly on the interplay between exchangeable cation and water in zones Am and B. This behavior can be separated into cations that do and do not form stable hydrates. Copyright 2004 by Marcel Dekker, Inc. All Rights Reserved. For stable hydrates, the strength of zone B water depends on exchangeable cation polarization power. , Al3)ם, the more acidic the associated hydration shell (Am) and the greater is the extension of zone B. Many of the properties of Al-smectites, for example, result from the high activity of zone B water (58).
43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. J Sanz, JL Robert. Phys Chem Minerals 1992; 19:39–45. HD Morris, S bank, PD Ellis. J Phys Chem 1990; 94:3121–3129. S Komarneni, CA Fyfe, GJ Kennedy, H Strobl. J Am Ceram Soc 1986; 69:C45–47. KA Carrado, R Csencsits, P Thiyagarajan, S Seifert, SM Macha, JS Harwood. J Mater Chem 2002; 12:3228–3237. KA Carrado, L Xu, DM Gregory, K Song, S Seifert, RE Botto. Chem Mater 2000; 12:3052–3059. J Grandjean, JL Robert. J Magn Reson 1999; 138:43–47. DJ Sullivan, JS Shore, JA Rice.