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By Stefan Hecht, Ivan Huc
This actually finished treatise of foldamers, from synthesis to functions in bio-, material-, and nanoscience is immediately an creation to the subject, whereas supplying in-depth money owed on a variety of points essentially aimed toward the specialist.
The booklet is obviously dependent, with the 1st half focusing on constitution and foldamer layout strategies, whereas the second one half covers practical elements from houses to purposes. The foreign workforce of specialist authors presents overviews of man-made ways in addition to analytical techniques.Content:
Chapter 1 Foldamers in response to neighborhood Conformational personal tastes (pages 1–33): Dr. Ivan Huc and Louis Cuccia
Chapter 2 Foldamers according to distant Intrastrand Interactions (pages 35–74): Philippe Le Grel and Gilles Guichard
Chapter three Foldamers in line with Solvophobic results (pages 75–108): Yan Zhao and Jeffrey S. Moore
Chapter four Foldamer Hybrids: outlined Supramolecular constructions from versatile Molecules (pages 109–146): Carsten Schmuck and Thomas Rehm
Chapter five keep watch over of Polypeptide Chain Folding and meeting (pages 147–171): Rajkishor Rai and Padmanabhan Balaram
Chapter 6 Simulation of Folding Equilibria (pages 173–192): Wilfred F. van Gunsteren and Zrinka Gattin
Chapter 7 Foldamer?based Molecular popularity (pages 193–228): Jorge Becerril, Johanna M. Rodriguez, Ishu Saraogi and Andrew D. Hamilton
Chapter eight organic functions of Foldamers (pages 229–265): Marc Koyack and Richard Cheng
Chapter nine Protein layout (pages 267–289): Jean?Luc Jestin and Frederic Pecorari
Chapter 10 Nucleic Acid Foldamers: layout, Engineering and choice of Programmable Biomaterials with reputation, Catalytic and Self?assembly houses (pages 291–329): Arkadiusz Chworos and Luc Jaeger
Chapter eleven Helically Folding Polymers (pages 331–366): Eiji Yashima and Katsuhiro Maeda
Chapter 12 Polyisocyanides: Stiffened Foldamers (pages 367–402): Matthijs B.J. Otten, Gerald A. Metselaar, Jeroen J.L.M. Cornelissen, Alan E. Rowan and Roeland J.M. Nolte
Chapter thirteen Foldamers at Interfaces (pages 403–425): Jan van Esch, Hennie Valkenier, Sebastian Hartwig and Stefan Hecht
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In the solid state, these oligomers adopt folded ladder-like conformations consisting of a pseudo-helical arrangement of imide or urea moieties around a central column of stacked aryl groups (Figs. 10a, b and d) [81, 117]. Tertiary amides give rise to less pronounced kinks and thus less pronounced interactions between adjacent aryl groups in the sequence. 4 Semi-rigid Backbones Fig. 10 Formulae and crystal structures at the same scale of tertiary ureas, amide and imide oligomers. (a)–(b) front view and side view; (c) top view and side view; (d) two possible conformations.