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By G. Venkataraman
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Additional resources for The Big and the Small: v. 1: Journey into the Microcosm - The Story of Elementary Particles
Sample text
12 are facetted. 12 Faceted ceria, CeO2 nanoparticles. In high-temperature processes, the formation of facets connected to sharp edges is possible only in the case of low vapor pressure of the material. Courtesy Nanophase Technologies Corporation, USA. Certainly, the formation of particle shapes is not monocausal. There are more phenomena influencing the shape of particles. It is well known that different crystallographic planes have different surface energies, for example, in cubic systems, the planes forming a cube have the lowest surface energy.
7 Typical setup for synthesis using the inert-gas condensation process. In a vacuum vessel, filled, at reduced pressure, with an inert gas, a metal is evaporated. In the gas atmosphere, the metal vapor is thermalized. The metal atoms lose thermal energy by collision with the inert gas atoms, and form nanoparticles. In a temperature gradient, the product moves to a liquidnitrogen-cooled finger by thermophoresis and is collected from the surface of the cold finger. the system to oxidize the metal powder slowly.
If necessary, this design allows further processing of the product without breaking the extremely pure conditions. 7 Typical setup for synthesis using the inert-gas condensation process. In a vacuum vessel, filled, at reduced pressure, with an inert gas, a metal is evaporated. In the gas atmosphere, the metal vapor is thermalized. The metal atoms lose thermal energy by collision with the inert gas atoms, and form nanoparticles. In a temperature gradient, the product moves to a liquidnitrogen-cooled finger by thermophoresis and is collected from the surface of the cold finger.