Supercooling by P. Wilson

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Journal of Experimental Biology, Vol. 206, 215-221. A. (2011a) Cold tolerance. N. A. ), pp. 182-204, CABI Publishing, ISBN 9781845936877, Wallingford. A. (2011b) Cold tolerance of New Zealand alpine insects. Journal of Insect Physiology, Vol. 57, 1090-1095, ISSN 0022-1910. W. & Ramløv, H. (1995) Hemolymph ice nucleating proteins from the New Zealand alpine weta Hemideina maori (Orthoptera: Stenopelmatidae). Comparative Biochemistry and Physiology B, Vol. 112, 535-542. J. A. (1997) Ice nucleation activity in a New Zealand alpine cockroach Celatoblatta quinquemaculata (Dictyoptera: Blattidae).

5 42 Supercooling mol/kg in Fig. 10(a) and (b). The appearance of the chart in Fig. 10(a) was similar to that of C8Glu system of Group (I) stated in Fig. 8 and Fig. 10(b) was to that of Group (II), respectively, although their sample situations were different in terms of their constituent and concentration. R2 O (1) R 1 = (2) R 1 = (3) R 1 = (4) R 1 = R1 O R2 R2 O O R2 R2 R 2 = OH (Raf finose) OH O OTr, R 2 = OH OTr, R 2 = OBn HO OH, R2 = OBn R2 R2 OH O OH O OH O HO HO O R2 R2 O CH 3 O OH O HO R2 OH (5) C12Raf Scheme 2.

6 (wt%) B A Temp. 8 1 C8Glu mole fraction Fig. 6. Relationships of phase transition behavior between lamellar phase and isotropic solution with C8Glu fraction. Coexistence region Continuous water layer Non-continuous water Water layer Water layer Region C B A ΔCp at Tg ΔH of phase transition Temp. of phase transition C8Glu mole fraction Fig. 7. Schematic figure of C8Glu/water mixture systems with variation of C8Glu concentration. Glass Transition Behavior of Aqueous Solution of Sugar-Based Surfactants 39 Region A: The water molecules would be present in a non-continuous state.

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