
By Pierre Delhaes(auth.)
Content material:
Chapter 1 A old review (pages 1–24):
Chapter 2 Polymorphism of Crystalline levels (pages 25–59):
Chapter three Non?Crystalline Carbons (pages 61–96):
Chapter four by-product Compounds and Analogs (pages 97–126):
Chapter five From fragrant Precursors to the Graphene airplane (pages 127–167):
Chapter 6 normal Structural houses (pages 169–215):
Chapter 7 digital constructions and Magnetic homes (pages 217–264):
Chapter eight digital shipping houses (pages 265–319):
Chapter nine Optical homes and their functions (pages 321–367):
Chapter 10 Vibrational homes (pages 369–408):
Chapter eleven floor and Interface Phenomena (pages 409–459):
Chapter 12 Chemical Reactivity and floor therapy (pages 461–502):
Chapter thirteen Divided and Porous Carbons (pages 503–552):
Chapter 14 Carbon Filaments, Composites and Heterogenous Media (pages 553–590):
Chapter 15 Use of Carbon fabrics (pages 591–630):
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Extra info for Carbon-based Solids and Materials
Sample text
Proc. Roy. Soc. (London), vol. A89, p. 277, 1913. , L’Actualité Chimique, vol. 3, pp. 30-36, 1999. , Phys. Rev. Lett, vol. 90, 155504-1, 2003. , Carbon, vol. 41, pp. 1877-1880, 2003. , A New System of Chemical Philosophy, part 1, R. BICKERSTAFF, London, 1808. , Chapter 2, in P. BERNIER and S. ), Le carbone dans tous ses états, Gordon and Breach Science Publishers, London, 1997, pp. 41-82. W. PATRICK, Porosities in Carbons, Edward Arnold, London 1995, pp. 227-252. [CAR 02] CARTIGNY P. “Les diamants”, dossier hors série, Pour la Science, April-June 2002.
Finally, a last point concerns single-walled carbon nanotubes (SWCNTs) and their assembly into organized bundles. Hence, such 2D triangular structures of nanotubes have been observed by electron diffraction showing a structure similar to those of crystallized polymers [JOU 97]. 5 for example). Alternatively a shockwave, created by an explosion, is an efficient experimental way to prepare allotropic varieties of diamond. The experimental research for these new 3D phases, which could be extremely hard, will be discussed at the end of this chapter.
Schwarzites As stated previously, infinite triperiodic structures with a negative Gaussian curvature and an average curvature equal zero can exist when built on seven to eight-membered rings. 10; they have large unit cells and therefore each of them contain a large number of atoms. 3 through a comparison with fullerenes and analogs. Two conclusions are therefore formulated: – the excess of cohesive energy, relative to hexagonal graphite and for the calculation conditions, is low for both types of schwarzites compared to C60; they would be a priori in a less metastable state without any assumptions regarding the activation energy applied in a possible fabrication process; – the modulus of rigidity calculated is smaller than that found for adamantane and is associated with a lower density; therefore, it can be assumed that these phases will not have remarkable hardness.