Advances in Photochemistry, Volume 2 by Noyes W

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For instance, at -lOO°C. the oxygen atom concentration may drop by one power of ten a t a distance of 10 cm. from the nozzle. Thus, in order that all atoms admitted through the nozzle react with CO, it is necessary to add CO in a rather high concentration. I n order to ascertain that a t a given CO flow rate the (Con), concentration determined experimentally equals that of initial oxygen atoms, a curve was plotted for COa accumulation as a function of the CO flow rate (Fig. 2). 2, to a pressure of molecular oxygen in the flow 4 mm.

57 7. Regular Relation between Activation Energies and of Pre-Exponential 58 Factors for Elementary Reactions. References. . . . . . . . . . . . . . . . . . . . . . . . . . . . ' This is due to the fact that initial substances are converted into end products not directly, but through a number of intermediate steps. With chain and radical reactions (including photochemical ones) the intermediate steps are elementary reactions of atoms and radicals with molecules.

D = D,; F = F,, gives expressions for the values of B,, C,, D,, and F as functions of &. The values B,, C,, D,, F, were plotted vs. ADfor various rate constants involved in equations for B,, C,, etc. The final concentrations of B,, D , and F,products as a function of A. , a case is taken when the initial substance gives one primary product. The difference in primary, quadratic, and cubic reaction product curves may be seen from Figure 3. While the function of the final concentration of the primary product corresponds to a curve tending to the limit, the functions of final concentrations of quadratic and cubic products correspond to curves having maxima.

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